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Den otevřených dveří 2025
9. 10. 2024
Chcete vidět naživo např. jaderný reaktor, urychlovač jader či zavítat na Centrum instrumentálních technik Ústavu anorganické chemie a [...]
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39th NARECOM
7. 10. 2024
The presentation "Application of X-ray diffraction in material analysis" will be introduced by Dr. Josef Kašlík from Palacký University [...]
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IIC Science Café
24. 9. 2024
We warmly invite you to the IIC Science Café seminar, which will be held on 10/10/2024 at 10 am at the IIC of the CAS in Řež. The [...]
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Záběry ze ZMJ 2024
24. 9. 2024
Výbuchy, dílničky, zmrzlina, hudba, přátelé - o víkendu jsme s vámi mohli Zažít město jinak v Cukrovarnické na Praze 6. Děkujeme [...]
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Novinky ve výzkumu
Experimental and Computational 77Se NMR Spectroscopic Study on Selenaborane Cluster Compounds
The study investigates the correlation between calculated and measured 77Se NMR chemical shifts in various selenaborane cluster compounds, showing that low-level quantum chemical calculations can reliably predict these shifts. This predictive ability helps in understanding the molecular structure of selenaboranes and efficiently locating 77Se resonances in experimental data. The findings highlight how accurate prediction of […]
Catalytic dehalogenation with activated borane, a porous borane cluster polymer
Activated borane (ActB) is a metal- and halogen-free porous borane cluster polymer that effectively serves as a heterogeneous catalyst for hydrodehalogenation of aliphatic fluorides and chlorides, using triethylsilane as a reductant. It demonstrates high thermal stability, reusability, and significant Lewis acidity, making it capable of achieving full dehalogenation with high turnover numbers, even after multiple […]
A Direct Route to closo-SBnCln Thiaboranes: Chalcogen Bonding in SB5Cl5 vs. SB11Cl11 Crystals
Polyhedral boron chemistry exhibits various heteroatom substitution and a series of heteroboranes thus being afforded Furthermore, the introduction of halogens instead of terminal hydrogens enables the synthesis of small perhalogenated heteroboranes, stabilized through π back-donation. In this research, SB5Cl5 and SB9Cl9 clusters were prepared by co-pyrolysis of B2Cl4 with S2Cl2 at 280 °C in a […]