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Školení CETAV
6. 11. 2024
Rádi bychom vás pozvali na školení s názvem „Služby CETAV v oblasti transferu znalostí“, které se uskuteční dne 13.11.2024 od 9:00 hod [...]
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40th NARECOM
6. 11. 2024
The presentation "Photocatalysis – Principle and Application in Water and Air Purification" will be introduced by Dr. Eliška [...]
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Den otevřených dveří 2024
9. 10. 2024
Chcete vidět naživo např. jaderný reaktor, urychlovač jader či zavítat na Centrum instrumentálních technik Ústavu anorganické chemie a [...]
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39th NARECOM
7. 10. 2024
The presentation "Application of X-ray diffraction in material analysis" will be introduced by Dr. Josef Kašlík from Palacký University [...]
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Novinky ve výzkumu
Experimental and Computational 77Se NMR Spectroscopic Study on Selenaborane Cluster Compounds
The study investigates the correlation between calculated and measured 77Se NMR chemical shifts in various selenaborane cluster compounds, showing that low-level quantum chemical calculations can reliably predict these shifts. This predictive ability helps in understanding the molecular structure of selenaboranes and efficiently locating 77Se resonances in experimental data. The findings highlight how accurate prediction of […]
Catalytic dehalogenation with activated borane, a porous borane cluster polymer
Activated borane (ActB) is a metal- and halogen-free porous borane cluster polymer that effectively serves as a heterogeneous catalyst for hydrodehalogenation of aliphatic fluorides and chlorides, using triethylsilane as a reductant. It demonstrates high thermal stability, reusability, and significant Lewis acidity, making it capable of achieving full dehalogenation with high turnover numbers, even after multiple […]
A Direct Route to closo-SBnCln Thiaboranes: Chalcogen Bonding in SB5Cl5 vs. SB11Cl11 Crystals
Polyhedral boron chemistry exhibits various heteroatom substitution and a series of heteroboranes thus being afforded Furthermore, the introduction of halogens instead of terminal hydrogens enables the synthesis of small perhalogenated heteroboranes, stabilized through π back-donation. In this research, SB5Cl5 and SB9Cl9 clusters were prepared by co-pyrolysis of B2Cl4 with S2Cl2 at 280 °C in a […]