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Preparation of porous coordination polymers using linkers containing phosphinate donor groups
6. 11. 2019
We discovered a new group of porous coordination polymers (MOFs). These materials may find use in preservation and separation of gases [...]
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Fluorescent “dragon” molecule, aka extraordinary thermochromic fluorescent borane
6. 11. 2019
A new chemical compound, B18H20(NC5H5)2, the unusual molecular structure of which resembles a flying dragon with its body consisting of [...]
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Degradation of toxic organophosphates on the surface of composite adsorbents
6. 11. 2019
Materials based on TiO2 nano particles with grapheme oxide prepared by means of unique methods developed at ÚACH can bind and [...]
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Porphyrin polymers for antibacterial surfaces
6. 11. 2019
Microbial colonies on the surfaces of medical devices contribute to outbreaks of serious patient infections. This is why we designed [...]
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What’s new in research
Experimental and Computational 77Se NMR Spectroscopic Study on Selenaborane Cluster Compounds
The study investigates the correlation between calculated and measured 77Se NMR chemical shifts in various selenaborane cluster compounds, showing that low-level quantum chemical calculations can reliably predict these shifts. This predictive ability helps in understanding the molecular structure of selenaboranes and efficiently locating 77Se resonances in experimental data. The findings highlight how accurate prediction of […]
Catalytic dehalogenation with activated borane, a porous borane cluster polymer
Activated borane (ActB) is a metal- and halogen-free porous borane cluster polymer that effectively serves as a heterogeneous catalyst for hydrodehalogenation of aliphatic fluorides and chlorides, using triethylsilane as a reductant. It demonstrates high thermal stability, reusability, and significant Lewis acidity, making it capable of achieving full dehalogenation with high turnover numbers, even after multiple […]
A Direct Route to closo-SBnCln Thiaboranes: Chalcogen Bonding in SB5Cl5 vs. SB11Cl11 Crystals
Polyhedral boron chemistry exhibits various heteroatom substitution and a series of heteroboranes thus being afforded Furthermore, the introduction of halogens instead of terminal hydrogens enables the synthesis of small perhalogenated heteroboranes, stabilized through π back-donation. In this research, SB5Cl5 and SB9Cl9 clusters were prepared by co-pyrolysis of B2Cl4 with S2Cl2 at 280 °C in a […]