Nothing Found

It seems we can’t find what you’re looking for. Perhaps searching can help.

What’s new in research



Catalytic dehalogenation with activated borane, a porous borane cluster polymer

Activated borane (ActB) is a metal- and halogen-free porous borane cluster polymer that effectively serves as a heterogeneous catalyst for hydrodehalogenation of aliphatic fluorides and chlorides, using triethylsilane as a reductant. It demonstrates high thermal stability, reusability, and significant Lewis acidity, making it capable of achieving full dehalogenation with high turnover numbers, even after multiple […]

A Direct Route to closo-SBnCln Thiaboranes: Chalcogen Bonding in SB5Cl5 vs. SB11Cl11 Crystals

Polyhedral boron chemistry exhibits various heteroatom substitution and a series of  heteroboranes thus being afforded Furthermore, the introduction of halogens instead of terminal hydrogens  enables the synthesis of small perhalogenated heteroboranes, stabilized through π back-donation. In this research, SB5Cl5 and SB9Cl9 clusters were prepared by co-pyrolysis of B2Cl4 with S2Cl2 at 280 °C in a […]

Zr-based MOFs: relation between linkers connectivity, stability, and catalytic activity

Metal–organic frameworks (MOFs) are widely researched but applied only in few commercial processes among others due to unknown stability. This study evaluates the stability of four zirconium-based MOFs with different linkers in water at pH 3.0 to 11.0. Results indicate that MOFs with tetratopic linkers (PCN-222, MIP-200) are more stable than those with ditopic or […]

NanoEnvi

Strategie AV 21

V4F Projekt63

StBernard Project