Polyhedral boron chemistry exhibits various heteroatom substitution and a series of  heteroboranes thus being afforded Furthermore, the introduction of halogens instead of terminal hydrogens  enables the synthesis of small perhalogenated heteroboranes, stabilized through π back-donation. In this research, SB5Cl5 and SB9Cl9 clusters were prepared by co-pyrolysis of B2Cl4 with S2Cl2 at 280 °C in a […]