Staff list – UACH

RNDr. Josef Holub

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Phone:	311236999
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Department:	Department of Syntheses
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List of publications:	www.lib.cas.cz/arl/bibliografie/ asep/uach-t/0102661

Projekty

Number	Title	Years
22-03945S	Polyhedral (Car)boranes Cationic and Catalytically Applicable	2022-2024

Publikace

2023

Marco, J. F. - Dávalos-Prado, J. Z. - Hnyk, Drahomír - Holub, Josef - Oñ a, O. B. - Alcoba, D. R. - Ferrer, M. - Elguero, J. - Lain, L. - Torre, A. - Oliva-Enrich, J. M.; 2024, 8 (15), 13993-14004

McKee, M.L. - Vrána, J. - Holub, Josef - Fanfrlík, Jindřich - Hnyk, Drahomír; Molecules; 2023, 28 (8), 3645

Keller, W. - Sárosi, M. B. - Fanfrlík, Jindřich - Straka, Michal - Holub, Josef - McKee, M. L. - Hnyk, Drahomír; RSC Advances; 2023, 13 (28), 19627-19637

Horáček, O. - Dhaubhadel, U. - Holub, Josef - Grüner, Bohumír - Armstrong, D.W. - Kučera, R.; Chirality; 2023, 35 (12), 937-951

PERUMALLA, D., GHORAI, S., PAL, T., HNYK, Drahomír, HOLUB, Josef, JEMMIS, E. D. Rearrangement of dicarboranyl methyl cation to icosahedral C3B9H12+: An ab initio dynamics view. Journal of Computational Chemistry. 2023, 44(3), 256-260

2022

Fojt, Lukáš - Grüner, Bohumír - Holub, Josef - Havran, Luděk - Fojta, Miroslav; Journal of Electroanalytical Chemistry; 2022, 910 (APR), 116165

Holub, Josef - Bakardjiev, Mario - McKee, M.L. - Hnyk, Drahomír; Inorganica chimica acta; 2022, 538 (AUG), 121000

Horáček, O. - Marvalová, J. - Štilcová, K. - Holub, Josef - Grüner, Bohumír - Kučera, R.; Journal of Chromatography A; 2022, 1672 (JUN), 463051

2021

BAKARDJIEV, Mario, HOLUB, Josef, BAVOL, Dmytro, VRÁNA, J., SAMSONOV, M. A., RŮŽIČKA, A., RŮŽIČKOVÁ, Z., FANFRLÍK, Jindřich, HNYK, Drahomír. Thiaborane Icosahedral Barrier Increased by the Functionalization of all Terminal Hydrogens in closo-1-SB11H11. Inorganic Chemistry. 2021, 60(12), 8428-8431

BAKARDJIEV, Mario, HOLUB, Josef, RŮŽIČKOVÁ, Z., RŮŽIČKA, A., FANFRLÍK, Jindřich, ŠTÍBR, Bohumil, MCKEE, M.L., HNYK, Drahomír. Transformation of various multicenter bondings within bicapped-square antiprismatic motifs: Z-rearrangement. Dalton Transactions. 2021, 50(35), 12098-12106

ŠOLÍNOVÁ, Veronika, BRYNDA, Jiří, ŠÍCHA, Václav, HOLUB, Josef, GRÜNER, Bohumír, KAŠIČKA, Václav. Determination of acidity constants, ionic mobilities, and hydrodynamic radii of carborane-based inhibitors of carbonic anhydrases by capillary electrophoresis. Electrophoresis. 2021, 42(7/8), 910-919

KUGLER, Michael, NEKVINDA, Jan, HOLUB, Josef, EL ANWAR, Suzan, DAS, V., ŠÍCHA, Václav, POSPÍŠILOVÁ, Klára, FÁBRY, M., KRÁL, V., BRYNDA, Jiří, KAŠIČKA, Václav, HAJDÚCH, M., ŘEZÁČOVÁ, Pavlína, GRÜNER, Bohumír. Inhibitors of CA IX Enzyme Based on Polyhedral Boron Compounds. Chembiochem. 2021, 22(18), 2741-2761

VRÁNA, J., HOLUB, Josef, SAMSONOV, M. A., RŮŽIČKOVÁ, Z., CVAČKA, Josef, MCKEE, M.L., FANFRLÍK, Jindřich, HNYK, Drahomír, RŮŽIČKA, A. Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes. Nature Communications. 2021, 12(1), 4971

GRÜNER, Bohumír, KUGLER, Michael, EL ANWAR, Suzan, HOLUB, Josef, NEKVINDA, Jan, BAVOL, Dmytro, RŮŽIČKOVÁ, Z., POSPÍŠILOVÁ, K., FÁBRY, Milan, KRÁL, Vlastimil, BRYNDA, Jiří, ŘEZÁČOVÁ, P. Cobalt Bis(dicarbollide) Alkylsulfonamides: Potent and Highly Selective Inhibitors of Tumor Specific Carbonic Anhydrase IX. ChemPlusChem. 2021, 86(3), 352-363

2020

HAVRÁNEK, M., SAMSONOV, M. A., HOLUB, Josef, RŮŽIČKOVÁ, Z., DROŽ, L., RŮŽIČKA, A., FANFRLÍK, Jindřich, HNYK, Drahomír. The influence of halogenated hypercarbon on crystal packing in the series of 1-Ph-2-X-1,2-dicarba-closo-dodecaboranes (X = F, Cl, Br, I). Molecules. 2020, 25(5), 1200

ASSAF, K. I., HOLUB, Josef, BERNHARDT, E., OLIVA-ENRICH, J. M., FERNÁNDEZ PÉREZ, M. I., CANLE, M., SANTABALLA, J.A., FANFRLÍK, Jindřich, HNYK, Drahomír, NAU, W. M. Face-Fusion of Icosahedral Boron Hydride Increases Affinity to ??Cyclodextrin: closo,closo?[B21H18]? as an Anion with Very Low Free Energy of Dehydration. ChemPhysChem. 2020, 21(10), 971-976

DVOŘANOVÁ, J., KUGLER, Michael, HOLUB, Josef, ŠÍCHA, Václav, DAS, V., NEKVINDA, Jan, EL ANWAR, Suzan, HAVRÁNEK, M., POSPÍŠILOVÁ, Klára, FÁBRY, M., KRÁL, V., MEDVEDÍKOVÁ, M., MATĚJKOVÁ, Stanislava, LIŠKOVÁ, B., GURSKÁ, S., DŽUBÁK, P., BRYNDA, J., HAJDÚCH, M., GRÜNER, Bohumír, ŘEZÁČOVÁ, Pavlína. Sulfonamido carboranes as highly selective inhibitors of cancer-specific carbonic anhydrase IX. European Journal of Medicinal Chemistry. 2020, 200(Aug 15), 112460

HOLUB, Josef, RŮŽIČKA, A., RŮŽIČKOVÁ, Z., FANFRLÍK, Jindřich, HNYK, Drahomír, ŠTÍBR, Bohumil. Electrophilic Methylation of Decaborane(14): Selective Synthesis of Tetramethylated and Heptamethylated Decaboranes and Their Conjugated Bases. Inorganic Chemistry. 2020, 59(15), 10540-10547

HOLUB, Josef, VISHNEVSKIY, Y. V., FANFRLÍK, Jindřich, MITZEL, N. W., TIKHONOV, D., SCHWABEDISSEN, J., MCKEE, M.L., HNYK, Drahomír. Bromination Mechanism of closo-1,2-C2B10H12 and the Structure of the Resulting 9-Br-closo-1,2-C2B10H11 Determined by Gas Electron Diffraction. ChemPlusChem. 2020, 85(12), 2606-2610

KUGLER, Michael, HOLUB, Josef, BRYNDA, Jiří, POSPÍŠILOVÁ, Klára, EL ANWAR, Suzan, BAVOL, Dmytro, HAVRÁNEK, M., KRÁL, V., FÁBRY, M., GRÜNER, Bohumír, ŘEZÁČOVÁ, Pavlína. The structural basis for the selectivity of sulfonamido dicarbaboranes toward cancer-associated carbonic anhydrase IX. Journal of Enzyme Inhibition and Medicinal Chemistry. 2020, 35(1), 1800-1810

HOLUB, Josef, FANFRLÍK, Jindřich, MCKEE, M.L., HNYK, Drahomír. Reactions of experimentally known closo-C2B8H10 with bases. A computational study. Crystals. 2020, 10(10), 896

NEKVINDA, Jan, KUGLER, Michael, HOLUB, Josef, EL ANWAR, Suzan, BRYNDA, Jiří, POSPÍŠILOVÁ, K., RŮŽIČKOVÁ, Z., ŘEZÁČOVÁ, Pavlína, GRÜNER, Bohumír. Direct Introduction of an Alkylsulfonamido Group on C-sites of Isomeric Dicarba-closo-dodecaboranes: The Influence of Stereochemistry on Inhibitory Activity against the Cancer-Associated Carbonic Anhydrase IX Isoenzyme. Chemistry - A European Journal. 2020, 26(69), 16541-16553

2019

BAKARDJIEV, Mario, RŮŽIČKA, A., RŮŽIČKOVÁ, Z., TOK, Oleg L., HOLUB, Josef, HNYK, Drahomír, FANFRLÍK, Jindřich, ŠTÍBR, Bohumil. Synthesis of closo-1,2-H2C2B8Me8 and 1,2-H2C2B8Me7X (X = I and OTf) Dicarbaboranes and Their Rearrangement Reactions. Inorganic Chemistry. 2019, 58(4), 2865-2871

BAŠE, Tomáš, HOLUB, Josef, FANFRLÍK, Jindřich, HNYK, Drahomír, LANE, P. D., WANN, D. A., VISHNEVSKIY, Y. V., TIKHONOV, D. S., REUTER, C. G., MITZEL, N. W. Icosahedral Carbaboranes with Peripheral Hydrogen–Chalcogenide Groups: Structures from Gas Electron Diffraction and Chemical Shielding in Solution. Chemistry - A European Journal. 2019, 25(9), 2313-2321

GRÜNER, Bohumír, BRYNDA, Jiří, DAS, V., ŠÍCHA, Václav, ŠTĚPÁNKOVÁ, J., NEKVINDA, Jan, HOLUB, Josef, POSPÍŠILOVÁ, B., FÁBRY, Milan, PACHL, P., KRÁL, Vlastimil, KUGLER, M., MAŠEK, V., MEDVĚDIKOVÁ, M., MATĚJKOVÁ, S., NOVÁ, A., LIŠKOVÁ, B., GURSKÁ, S., DŽUBÁK, P., HAJDÚCH, M., ŘEZÁČOVÁ, Pavlína. Metallacarborane sulfamides: Unconventional, specific, and highly selective inhibitors of carbonic anhydrase IX. Journal of Medicinal Chemistry. 2019, 62(21), 9560-9575

PRUDILOVÁ, B., OTYEPKOVÁ, E., FANFRLÍK, Jindřich, HNYK, Drahomír, HOLUB, Josef, PETR, M., FILIP, J., ČÉPE, K., LAZAR, P., OTYEPKA, M. Surface termination of MgB2 unveiled by a combination of adsorption experiments and theoretical calculations. Physical Chemistry Chemical Physics. 2019, 21(14), 7313-7320

VRÁNA, J., HOLUB, Josef, RŮŽIČKOVÁ, Z., FANFRLÍK, Jindřich, HNYK, Drahomír, RŮŽIČKA, A. Investigation of Thiaborane closo- nido Conversion Pathways Promoted by N-Heterocyclic Carbenes. Inorganic Chemistry. 2019, 58(4), 2471-2482

VRÁNA, J., HOLUB, Josef, SAMSONOV, M. A., RŮŽIČKOVÁ, Z., FANFRLÍK, Jindřich, HNYK, Drahomír, RŮŽIČKA, A. Thiaborane clusters with an exoskeletal B-H group. Chemical Communications. 2019, 55(23), 3375-3378

HOLUB, Josef, VRÁNA, J., RŮŽIČKA, A., RŮŽIČKOVÁ, Z., FANFRLÍK, Jindřich, HNYK, Drahomír. Thiaboranes on Both Sides of the Icosahedral Barrier: Retaining and Breaking the Barrier with Carbon Functionalities. ChemPlusChem. 2019, 84(7), 822-827

FRANCES-MONERRIS, A., HOLUB, Josef, ROCA-SANJUAN, D., HNYK, Drahomír, LANG, Kamil, OLIVA-ENRICH, J. M. Photochromic System among Boron Hydrides: The Hawthorne Rearrangement. Journal of Physical Chemistry Letters. 2019, 10(20), 6202-6207

EL ANWAR, Suzan, ASSAF, K. I., BEGAJ, B., SAMSONOV, M. A., RŮŽIČKOVÁ, Z., HOLUB, Josef, BAVOL, Dmytro, NAU, W. M., GABEL, D., GRÜNER, Bohumír. Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules, host-guest complexation with ?-cyclodextrin. Chemical Communications. 2019, 55(91), 13669-13672

2018

BAKARDJIEV, Mario, ŠTÍBR, Bohumil, TOK, Oleg L., HOLUB, Josef. Unusual Closure of the Ten-Vertex Nido Cage via Alkylation: Regiospecific Synthesis of 3-Alkyl Derivatives of closo-1,2-C2B8H10. Inorganic Chemistry. 2018, 57(3), 1368-1372

BAKARDJIEV, Mario, TOK, Oleg L., RŮŽIČKA, A., RŮŽIČKOVÁ, Z., HOLUB, Josef, HNYK, Drahomír, ŠPALT, Zbyněk, FANFRLÍK, Jindřich, ŠTÍBR, Bohumil. Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues. Dalton Transactions. 2018, 47(32), 11070-11076

BAKARDJIEV, Mario, TOK, Oleg L., RŮŽIČKA, A., RŮŽIČKOVÁ, Z., HOLUB, Josef, HNYK, Drahomír, FANFRLÍK, Jindřich, ŠTÍBR, Bohumil. Quantitative syntheses of permethylated closo-1,10-R2C2B8Me8 (R = H, Me) carboranes. Egg-shaped hydrocarbons on the Frontier between inorganic and organic chemistry. RSC Advances. 2018, 8(67), 38238-38244

TOK, Oleg L., HOLUB, Josef, RŮŽIČKA, A., RŮŽIČKOVÁ, Z., ŠTÍBR, Bohumil. Direct synthesis of dicarbollides. New Journal of Chemistry. 2018, 42(11), 8524-8529

EL ANWAR, Suzan, HOLUB, Josef, TOK, Oleg L., JELÍNEK, T., RŮŽIČKOVÁ, Z., FOJT, Lukáš, ŠOLÍNOVÁ, Veronika, KAŠIČKA, Václav, GRÜNER, Bohumír. Synthesis and selected properties of nonahalogenated 2-ammonio-decaborate anions and their derivatives substituted at N-centre. Journal of Organometallic Chemistry. 2018, 865(SI), 189-199

OLIVA-ENRICH, J. M., HUMBEL, S., SANTABALLA, J.A., ALKORTA, I., NOTARIO, R., DÁVALOS, J. Z., CANLE-L., M., BERNHARDT, E., HOLUB, Josef, HNYK, Drahomír. Predicted Gas-Phase and Liquid-Phase Acidities of Carborane Carboxylic and Dicarboxylic Acids. ChemistrySelect. 2018, 3(16), 4344-4353

ŠVEC, P., CATTEY, H., RŮŽIČKOVÁ, Z., HOLUB, Josef, RŮŽIČKA, A., PLASSERAUD, L. Triorganotin(iv) cation-promoted dimethyl carbonate synthesis from CO2and methanol: Solution and solid-state characterization of an unexpected diorganotin(iv)-oxo cluster. New Journal of Chemistry. 2018, 42(10), 8253-8260

HOLUB, Josef, RŮŽIČKOVÁ, Z., HOBZA, Pavel, FANFRLÍK, Jindřich, HNYK, Drahomír, RŮŽIČKA, A. Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt. New Journal of Chemistry. 2018, 42(13), 10481-10483

MELÁNOVÁ, Klára, HOLUB, Josef, HYNEK, Jan, FANFRLÍK, Jindřich, BENEŠ, L., KUTÁLEK, P., KREJČOVÁ, A., HNYK, Drahomír, ZIMA, Vítězslav. Outerly functionalized and non-functionalized boron clusters intercalated into layered hydroxides with different modes of binding: materials for superacid storage. Dalton Transactions. 2018, 47(33), 11669-11679

Oliva-Enrich, J. M. - Humbel, S. - Dávalos, J. Z. - Holub, Josef - Hnyk, Drahomír, 2018: OLIVA-ENRICH, J. M., HUMBEL, S., DÁVALOS, J. Z., HOLUB, Josef, HNYK, Drahomír. Proton affinities of amino group functionalizing 2D and 3D boron compounds. Afinidad. 2018, 75(584), 260-266

2017

BAKARDJIEV, Mario, RŮŽIČKA, A., RŮŽIČKOVÁ, Z., HOLUB, Josef, TOK, Oleg L., ŠTÍBR, Bohumil. Electrophilic Halogenation of closo-1,2-C2B8H10. Inorganic Chemistry. 2017, 56(10), 5971-5975

ŠTÍBR, Bohumil, TOK, Oleg L., HOLUB, Josef. Quantitative Assessment of Substitution NMR Effects in the Model Series of o-Carborane Derivatives: alpha-Shift Correlation Method. Inorganic Chemistry. 2017, 56(14), 8334-8340

ŠTÍBR, Bohumil, HOLUB, Josef, BAKARDJIEV, Mario, LANE, P. D., MCKEE, M., WANN, D. A., HNYK, Drahomír. Unusual cage rearrangements in 10-vertex nido-5,6-dicarbaborane derivatives: An interplay between theory and experiment. Inorganic Chemistry. 2017, 56(2), 852-860

EYRILMEZ, Saltuk M., BERNHARDT, E., DÁVALOS, J. Z., LEPŠÍK, Martin, HOBZA, Pavel, ASSAF, K. I., NAU, W. M., HOLUB, Josef, OLIVA-ENRICH, J. M., FANFRLÍK, Jindřich, HNYK, Drahomír. Binary twinned-icosahedral [B21H18](-) interacts with cyclodextrins as a precedent for its complexation with other organic motifs. Physical Chemistry Chemical Physics. 2017, 19(19), 11748-11752

HOLUB, Josef, EL ANWAR, Suzan, JELÍNEK, T., FOJT, Lukáš, RŮŽIČKOVÁ, Z., ŠOLÍNOVÁ, Veronika, KAŠIČKA, Václav, GABEL, D., GRÜNER, Bohumír. Polyhalogenated Decaborate and 1-Ammoniododecaborate Ions: An Improved Synthesis with Elemental Halogens, and Physicochemical and Chemical Properties. European Journal of Inorganic Chemistry. 2017, 2017(38/39), 4499-4509

HOLUB, Josef, MELICHAR, Petr, RŮŽIČKOVÁ, Z., VRÁNA, J., WANN, D. A., FANFRLÍK, Jindřich, HNYK, Drahomír, RŮŽIČKA, A. A novel stibacarbaborane cluster with adjacent antimony atoms exhibiting unique pnictogen bond formation that dominates its crystal packing. Dalton Transactions. 2017, 46(40), 13714-13719

2016

BAKARDJIEV, Mario, HOLUB, Josef, HNYK, Drahomír, ŠTÍBR, Bohumil, RŮŽIČKOVÁ, Z., RŮŽIČKA, A. An unexpected rearrangement of carbon vertexes in the tricarbollide series. Asymmetrical 7-aryl-nido-7,8,9-C3B8H11 derivatives. Journal of Organometallic Chemistry. 2016, 805(MAR), 117-121

BAKARDJIEV, Mario, ŠTÍBR, Bohumil, HOLUB, Josef, TOK, Oleg L., ŠVEC, Petr, RŮŽIČKOVÁ, Z., RŮŽIČKA, A. Sequential Camouflage of the arachno-6,9-C2B8H14 Cage by Substituents. Inorganic Chemistry. 2016, 55(14), 7068-7074

BAKARDJIEV, Mario, HOLUB, Josef, TOK, Oleg L., ŠTÍBR, Bohumil, HNYK, Drahomír, NEKVINDA, Jan, RŮŽIČKOVÁ, Z., RŮŽIČKA, A. Open-face alkylation of the 8-R-nido-7,8,9-C3B8H11 tricarbollides. Journal of Organometallic Chemistry. 2016, 822(NOV), 80-84

TOK, Oleg L., BAKARDJIEV, Mario, ŠTÍBR, Bohumil, HNYK, Drahomír, HOLUB, Josef, PADĚLKOVÁ, Z., RŮŽIČKA, A. Click Dehydrogenation of Carbon-Substituted nido-5,6-C2B8H12 Carboranes: A General Route to closo-1,2-C2B8H10 Derivatives. Inorganic Chemistry. 2016, 55(17), 8839-8843

FANFRLÍK, Jindřich, HOLUB, Josef, RŮŽIČKOVÁ, Z., ŘEZÁČ, Jan, LANE, P. D., WANN, D. A., HNYK, Drahomír, RŮŽIČKA, A., HOBZA, Pavel. Competition between Halogen, Hydrogen and Dihydrogen Bonding in Brominated Carboranes. ChemPhysChem. 2016, 17(21), 3373-3376

FOJT, Lukáš, FOJTA, Miroslav, HOLUB, Josef, GRÜNER, Bohumír, VESPALEC, Radim. Electrochemistry of different boranes, carbaboranes and their exo-skeletal hydroxy derivatives at the graphite carbon electrode in aqueous phosphate buffers. Electrochimica acta. 2016, 205(JUL 2016), 8-14

RŮŽIČKOVÁ, Z., HOLUB, Josef, MELICHAR, Petr, MONCOL, J., WANN, D. A., FANFRLÍK, Jindřich, RŮŽIČKA, A., HNYK, Drahomír. The pi Complex of the Hydronium Ion Frozen on the Pathway of Electrophilic Aromatic Substitution. European Journal of Organic Chemistry. 2016, 2016(26), 4473-4475

2015

BAKARDJIEV, Mario, HOLUB, Josef, MACHÁČEK, Jan, HNYK, Drahomír, ŠTÍBR, Bohumil, RŮŽIČKOVÁ, Z., RŮŽIČKA, A. Unique Stereocontrol in Carborane Chemistry: Skeletal Alkylcarbonation (SAC) versus Exoskeletal Alkylmethylation (EAM) Reactions. Angewandte Chemie - International Edition. 2015, 54(16), 4937-4940

VISHNEVSKIY, Y. V., TIKHONOV, D. S., REUTER, C. G., MITZEL, N. W., HNYK, Drahomír, HOLUB, Josef, WANN, D. A., LANE, P. D., BERGER, R. J. F., HAYES, S. A. Influence of Antipodally Coupled Iodine and Carbon Atoms on the Cage Structure of 9,12-I-2-closo-1,2-C2B10H10: An Electron Diffraction and Computational Study. Inorganic Chemistry. 2015, 54(24), 11868-11874

NUNES, J. P. F., HOLUB, Josef, RANKIN, D. W. H., WANN, D. A., HNYK, Drahomír. A computational analysis of the apparent nido vs. hypho conflict: Are we dealing with six- or eight-vertex open-face diheteroboranes? Dalton Transactions. 2015, 44(26), 11819-11826

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